Crystal structure of cis,fac-{N,N-bis­[(pyridin-2-yl)meth­yl]methyl­amine-κ3 N,N′,N′′}di­chlorido­(dimethyl sulfoxide-κS)ruthenium(II)

نویسندگان

  • Kasey Trotter
  • Navamoney Arulsamy
  • Elliott Hulley
چکیده

The reaction of di-chlorido-tetra-kis-(dimethyl sulfoxide)-ruthen-ium(II) with N,N-bis[(pyridin-2-yl)meth-yl]methyl-amine aff-ords the title complex, [RuCl2(C13H15N3)(C2H6OS)]. The asymmetric unit contains a well-ordered complex mol-ecule. The N,N-bis-[(pyridin-2-yl)meth-yl]methyl-amine (bpma) ligand binds the cation through its two pyridyl N atoms and one aliphatic N atom in a facial manner. The coordination sphere of the low-spin d (6) Ru(II) is distorted octahedral. The dimethyl sulfoxide (dmso) ligand coordinates to the cation through its S atom and is cis to the aliphatic N atom. The two chloride ligands occupy the remaining sites. The bpma ligand is folded with the dihedral angle between the mean planes passing through its two pyridine rings being 64.55 (8)°. The two N-Ru-N bite angles of the ligand at 81.70 (7) and 82.34 (8)° illustrate the distorted octa-hedral coordination geometry of the Ru(II) cation. Two neighboring molecules are weakly associated through mutual intermolecular hydrogen bonding involving the O atom and one of the methyl groups of the dmso ligand. One of the chloride ligands is also weakly hydrogen bonded to a pyridyl H atom of another molecule.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ3 C 2,N]iridium(III) aceto­nitrile monosolvate

The title compound, [IrCl(C12H8NO)2{(CH3)2SO}]·H3CCN or [IrCl(fppy)2(DMSO)]·H3CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octa-hedral coordination sphere. The complex crystallizes from 1:1 DMSO-aceto-ni...

متن کامل

cis,fac-Dichlorido{N-[3,5-di-tert-butyl-2-(trimethyl­silyl­oxy)benz­yl]-N,N-bis­(2-pyridylmeth­yl)amine}(dimethyl sulfoxide)ruthenium(II) dichloro­methane disolvate

Reaction of dichloridotetra-kis(dimethyl sulfoxide)ruthenium(II) and N-[3,5-di-tert-butyl-2-(trimethyl-silyl-oxy)benz-yl]-N,N-bis-(2-pyridylmeth-yl)amine (BPPA-TMS) affords the thermodynamic product cis,fac-[RuCl(2)(BPPA-TMS)(DMSO)] and kinetic product trans,mer-[RuCl(2)(BPPA-TMS)(DMSO)]. The title complex, [RuCl(2)(C(30)H(43)N(3)OSi)(C(2)H(6)OS)]·2CH(2)Cl(2), crystallizes as a dichloro-methane...

متن کامل

[(4-Methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine-κ3 N,N′,N′′]bis­(thio­cyanato-κS)copper(II) dichloro­methane hemisolvate

The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol-ecules (A and B) in the asymmetric unit, accompanied by one dichloro-methane solvent mol-ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine ligand and two from the thio-cyanate ligan...

متن کامل

Dichlorido{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}cadmium

In the title compound, [CdCl(2)(C(11)H(17)N(3))], the Schiff base acts as an N,N',N''-tridentate ligand towards the Cd(II) ion. Two Cl atoms complete a distorted square-pyramidal geometry around the metal atom. In the crystal, a C-H⋯Cl inter-action connects pairs of mol-ecules into centrosymetric dimers.

متن کامل

(Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate

In the title compound, [Co(CH(3)CO(2))(C(18)H(24)N(6))]PF(6), the Co(II) atom is penta-coordinated in a distorted trigonal-bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by inter-molecular C-H⋯F and C-H⋯O hydrogen bonds.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 71  شماره 

صفحات  -

تاریخ انتشار 2015